catena-Poly[[[(dimethylmalonato-κ2 O:O′)(perchlorato-κO)copper(II)]-μ-bis(3-pyridylmethyl)piperazinediium-κ2 N 1′:N 4′] perchlorate dihydrate]
نویسندگان
چکیده
In the title compound, {[Cu(C(5)H(6)O(4))(ClO(4))(C(16)H(22)N(4))]ClO(4)·2H(2)O}(n), square-pyramidally coordinated Cu atoms with perchlorate and dimethyl-malonate ligands are connected into cationic sinusoidal coordination polymer chains by doubly protonated bis-(3-pyridylmeth-yl)piperazine (3-bpmp) ligands. The chains aggregate into pseudo-layers parallel to the (101) crystal planes by N-H⋯O hydrogen bonding. Unligated perchlorate anions and water mol-ecules of crystallization provide additional hydrogen bonding between pseudo-layers.
منابع مشابه
catena-Poly[copper(II)-bis(μ-2-formyl-6-methoxyphenolato-κ4 O 2,O 1:O 1,O 6)-[(methanol-κO)sodium]-μ-perchlorato-κ2 O:O′]
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008